11/10/2023 0 Comments Zmatrix gaussian![]() ![]() ![]() The most-used Z-matrix format uses the following syntax: Element-label, atom 1, bond-length, atom 2, bond-angle, atom 3, dihedral-angle format-code Although these examples use commas to separate items within a line, any valid separator may be used. Since I use CFOUR (not GAUSSIAN), I know of this page that might help with learning about dummy atoms for Z-matrices (search for 'dummy'):. Post memes/jokes in /r/chemistrymemes and /r/chemistryjokes. Each line of a Z-matrix gives the internal coordinates for one of the atoms within the molecule. \begingroup QuantumX Okay, then if you're using ZMAT, there's always strange oddities that require dummy atoms (this is not just in Gaussian, but also in CFOUR, for example). It can also perform many related functions, such as extracting molecule specifications from Gaussian checkpoint files. Any such posts will be deleted.Īsk education and jobs questions in the current weekly topic. Description Syntax Options Examples The newzmat utility was designed primarily for converting molecule specifications between a variety of standard formats. Gaussian formatted checkpoint file format (fchk, fch, fck) This Page. Gaussian Output (g09, g03, g94, g92, g98, gal) Next topic. If you're looking for a more concentrated, advanced discussion of chemistry topics among professionals and grad students, check out /r/Chempros.īefore asking "What chemical is this?" see this chart. Gaussian Z-Matrix Input (gzmat) Read Options Write Options Previous topic. Click here for the OSHA chemical data site and here for a multicompany MSDS aggregate search. If you spill/injure yourself contact medical professionals and read the MSDS, do not post to this reddit. Yes links to blogs, images, videos, comics, and infographics are okay especially if they are on your personal website. No physorg, sciencedaily, or other press release aggregator spam! If a caption or explanation is included this helps, but please use your discretion.īefore asking about chemical drawing/illustration programs, look at your school's IT/software website and see if they provide an institutional license of ChemDraw (hint: if they have a chemistry department, they will) Sometimes it is a good idea to think before attempting to write a Z-matrix. We will show a few simple examples of how to make Z-matrices in this text. The parameters one needs are distances, angles and dihedral angles. ![]() Likewise, simple pictures of uninteresting and garden variety chemistry-related things are not appreciated. A Z-matrix is used to define connectivity between atoms in a molecule. No memes, rage comics, image macros, reaction gifs, or other "zero-content" material. However, academic discussions on pharmaceutical chemistry and the science of explosives are permitted. Rules: Violating a rule will result in a ban.Īsk homework, exam, lab, and other undergraduate-level questions at ChemicalForums otherwise it will be deleted.ĭiscussions on illicit drug synthesis, bomb making, and other illegal activities are not allowed and will lead to a ban. ![]()
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11/10/2023 0 Comments Elk county pa![]() Our 4D story theater gives guest the opportunity to get inside Pennsylvania's Elk Herd for a close up look at what goes on in their habitat. ![]() In addition we have interactive cameras of the property. Our center has 7 interactive touch screens that allow guests to learn about elk, wildlife and LEED. Mid day is when elk and almost all other wildlife move into the protection of the woods to avoid heat and insects. As noted everywhere, best opportunity for viewing is in the early morning hours and the hours before dark. Your arrival time would have prevented you from seeing elk. When we visited the employees and the visitors inside the building were wearing masks. Outside there are several short hiking trails to view points where elk may be seen depending on the time of day. A movie can be viewed for a $5 charge on the hour and half hour. There is a gift shop with a wide range of items available including snacks and bottled water and clean restrooms. The employees I spoke with were very willing to answer questions and offer suggestions as to where and when we could see the elk. There is literature available to help you to plan your visit to the area. Inside there are a variety of educational exhibits geared to children and adults. ![]() The Visitor Center is a "green" building set in a stunning location. It was a great place to become oriented to the area and learn about the plants and animals in the Pennsylvania Wilds. My husband and I visited the Elk County Visitor Center as our first stop on the Elk Scenic Drive. ![]() 11/10/2023 0 Comments Judith summertime saga![]() ![]() Mrs Smith's DNA - Go to Mrs Smith's office and talk to Annie.Failure will mean returning the next day until you can do so. When you return, Miss Okita will have you build some goggles but you will need to pass the Intelligence check in order to complete it successfully. The locker with the 'cow' sticky note on it is Judith's, so click on that one to grab the spare pair of glasses. If you don't already have the master key snag it from Mrs Smith's desk in her office before heading back to the locker hallway. She tells you to meet her at the park during the afternoon.Īt the park, Judith will be sitting on the bench to the left of the water fountain and will take a few pictures of the two of you together before telling you the glasses are in her locker. Talk to Judith in the locker hallway and she will let you have her spare pair if you pretend to be her boyfriend. The next day Miss Okita will send you off to find some multifocal lenses for her invention. You'll both watch Mia do an experiment which doesn't work out so well and Miss Okita will tell you to come back tomorrow. Go back to the science classroom and talk to Miss Okita again. ![]() You also need a labcoat which is slung over her PC under the desk and some gogles which are on the experiment table. Then use it on Miss Okita's door right next to Mrs Smith's.Ī small robot will interrupt you when you enter and eventually inform you the blueprints you need are behind you on the floor. Click on the small sticky note to get the keycode 6219. Updated a few Cookie Jar scenes that were showing art for the wrong time of day.Sneak into Mrs Smith's office when she's not there and go into her desk.Ensured that the correct background is used in the lead-out of Helen's second cookie jar scene.Corrected quirk with Cookie Jar rescue code to avoid future foot-gunning.Fixed problem with some sex scene dialogue not being played, or playing at the wrong time.Corrected small framing issue with animation assets.Scenes with variants will now indicate how many have been unlocked and the total available.Added one new micro quest with an all-new scene and repeatable variant.Each position has new unique sex dialogue.Expanded five existing scenes with six new animated positions.Make sure to watch our daily live stream to see the development! Thanks to those supporting us all this time, and those who send us all the feedback. You can check out what's being worked on (no spoilers, though!) and ask questions. Some of you are already aware, but I do development live streams during week days on our Picarto channel. Hints and (for those that want) instructions to find the new scenes can be found in the in-game changelog (click the version number on the main menu), by clicking on the line marked "Spoilers". Many of the new scenes are integrated into existing stories, as a result if you have already completed those stories in your save, you will need to use New Content mode to play them. If you are a not a Patron but want to play our latest patch, you will have to wait for our public links to be ready, roughly within 24 hours (OLD SAVES COMPATIBLE BUT SEE BELOW): If you are a Patron supporting us, you can access a unique private download link on our website by linking your Patreon account here (OLD SAVES COMPATIBLE BUT SEE BELOW): This small update adds a new short quest at the car dealership, 7 new animations, 250+ new and updated assets, 850+ lines of new dialogue, 3000+ lines of posing and supporting code. Happy Halloween! Here's a treat for those who have a sweet tooth. ![]() 11/9/2023 0 Comments Davinci resolve studio 16![]() ![]() If you’re at NAB, stop by our first-ever Frame.io booth at 2426 in South Lower to hear more about these announcements, and say “Hi” to our team!. You can now use the same API that our new DaVinci Resolve integration is built on to transform your own video workflow. This announcement is just one of many we shared today. If you don’t already have DaVinci Resolve Studio, you can download it here. DaVinci Resolve is a color grading, color correction, visual effects, and audio post-production video editing application for macOS, Windows, and Linux, developed by Blackmagic Design.It was originally developed by da Vinci Systems as da Vinci Resolve until 2009, when da Vinci Systems was acquired by Blackmagic Design. If you already have DaVinci Resolve Studio, you’ll be able to access Frame.io inside DaVinci Resolve 16 as soon as the new beta is released. There’s no further action needed from you.įrame.io in DaVinci Resolve will be available soon in open beta in the Studio (paid) version only. Everything happens automatically when exporting your timeline. Straight-forward media exports-no extra steps necessaryĮntire timelines, or just sections, can be rendered, batch uploaded and synced at the same time to Frame.io with ease. The collaboration synchronization is unlike any other integration we support, you can hold entire conversations between Frame.io and DaVinci Resolve without needing to switch contexts. If they reply to your comment, their threaded response will show up as a marker right in your timeline. If you leave a comment on your timeline in DaVinci Resolve, teammates and collaborators will see it in Frame.io. ![]() Resolve will automatically swap the proxy with the full resolution file.Īutomatically synced, frame-accurate commentsįrame.io comments, replies, and annotations are automatically synced to your DaVinci Resolve timeline, no import or export necessary. Any Frame.io clips added to the Media Pool are automatically downloaded for use in the project you’re working on-and you can even start cutting while the full resolution file is being downloaded in the background. With Frame.io in DaVinci Resolve, you’ll have access to all your Frame.io accounts, teams, projects, and folders right in the DaVinci Resolve Media tab, immediately on sign-in. Your entire Frame.io workspace in Resolve’s Media Storage It’s a major step in pushing the boundaries of cloud video workflows even further so that you can continue to make better video, faster. Today’s announcement marks another significant milestone not only for us, but for the entire professional video community. For years, we’ve supported integrations in the top advanced editing tools, including Premiere Pro and After Effects and just last Fall, we introduced an all-new workflow extension built into Final Cut Pro X in partnership with Apple. This launch has been a long time coming, and we know it’s something many of you have been eager to get your hands on. Built entirely on our now public API, this is much more than just an integrationㄧFrame.io is a native feature set tightly woven into the fabric of DaVinci Resolve Studio, zero installation required. When we say it’s natively integrated, we mean it. It’s the NAB show in Las Vegas and we just shared some incredible news in partnership with Blackmagic Design: Frame.io is now natively integrated into DaVinci Resolve Studio. ![]() 11/9/2023 0 Comments Matlab vs python syntax![]() ![]() Space of size 501 (points in $D_t$ ) x 21 (points in $Y_t^T$ x 11 In Matlab, it takes around 53 seconds to solve the VFI with a state Problem reduces to choosing both consumption and debt. States are debt ( $D_T$ ), tradable income shock ( $Y_t^T$ ), and Once you do the math, you can show that in this model, the relevant This model, a planner chooses the Optimal Exchange Rate to eliminate the ![]() To solve a model of an SOE with downward nominal wage rigidities. In particular, I adapted the example you gave us about optimal savings I've tried replicating some of my Matlab codes in Python + Numba. Files: OER.ipynb (solves the model by VFI), tpm.py (discretizes VAR) PythonVFIcode.zip.mat containing parameters), TransitionMatrix.m (discretizes the VAR process), vfi_OER.m (solves the model by VFI), tpm.m (Function required to discretize VAR) MatlabVFIcode.zip Matlab files: Folder "Matlab VFI code") which includes a script that runs everything up to timing the VFI function.Would you mind looking at my code and letting me know if you can spot something that might be causing the extra time? I know pure Python sometimes is slow, but since I'm using Numba, I don't know what might be happening. However, when I solved the VFI problem in Python (using jitted functions), it took 13 minutes and 16 seconds ( almost 14 times slower than Matlab!!!!) In Matlab, it takes around 39 seconds to solve the VFI with a state space of size 501 (points in $D_t$ ) x 21 (points in $Y_t^T$ x 11 (points in $r_t$). You forget about the wage, and the problem reduces to choosing both consumption and debt. Once you do the math, you can show that in this model, the relevant states are debt ( $D_T$ ), tradable income shock ( $Y_t^T$ ), and interest rate shock ( $r_t$ ). In this model, a planner chooses the Optimal Exchange Rate to eliminate the friction in the labor market. In particular, I adapted the example you gave us about optimal savings to solve a model of an SOE with downward nominal wage rigidities. Hi tried replicating some of my Matlab codes in Python + Numba. ![]() 11/9/2023 0 Comments Yumi ishiyama![]() ![]() 'Hiroki' is a Japanese word for "Abundant joy/strength".In A Space Oddity, Hiroki call Kiwi with "Leechie".Hiroki made his first appearance in Season 2 episode, Exploration.Judging by how much he plays video games, he seems to be a decent gamer.He and Johnny are both highly capable locksmiths, as revealed in Hot Shower. His best friend is Johnny, who has a crush on Yumi. ![]() Evolution Hiroki is mentioned in evolution but never seen. To help Hiroki apologize to his sister, Ulrich secretly returns the diary, but Yumi thinks it was Hiroki and forgives him. Season 4 In the episode Lost At Sea, Hiroki steals Yumi's diary and Ulrich finds it. Yumi Ishiyama is one of my favorite characters from CL and I hope to portray her well. Hiroki makes a brief appearance in The Key, answering the door for Ulrich, and asking Yumi if she is dating Ulrich yet. This causes Ulrich to get knocked unconcious by the monster. When Ulrich cut's off one of the monster's legs Hiroki runs towards him and the monster. Hiroki watches as his father and later Ulrich defends against the monster's attacks. In A Bad Turn, Hiroki call's Yumi to ask her to save him and his family from the big monster. He is later shown to be present when the Ishiyamas's win the lottery, through Ulrich's cheating. Hiroki's next appearance is in The Chips Are Down where he is at the table when his father says that he was unable to find work at the temp agency. Hiroki is present at the family's game night and is playing a video game on what appears to be a Nintendo DS. He is shown to be maddly in love with Milly, but does not know how to act on these feelings.īiography Season 2 Hiroki first appears in Exploration, in this episode he appears as a bratty little brother. He loves to ask Yumi "if she is dating ulrich?" He is shown to deeply care about Yumi when she is in danger. He will usually help Yumi in exchange for her doing him favors, such as doing his homework for him. He is portayed to be a somewhat mean to Yumi, but in a brotherly kind of way. Hiroki is usually portayed as a typical bratty brother. ![]() 11/9/2023 0 Comments Pathless pedaled![]() ![]() In one area called Ponsonby, we saw people would scurry out into the center of the street like a mouse and wait until the traffic was done then scurry to the other side. You would think in business districts businesses would want pedestrians to be able to cross the street. We were shocked when we saw the sign that peds must give way to cars. It's not perfect here in the states but in New Zealand cars have the right of way. RR- I missed pedestrian rights! That was a big shock. ![]() GK - What about some things you missed about the U.S.? Some people who were skeptical about cyclists and thought they would tip over their cows or light fields on fire became converts because they saw the positive impact the cyclists were having on the community and local economy. RR - I'd say the Otago Central Rail Trail because it is a great example of using bike tourism to revitalize areas along the way. It can be headache with a full size bike, but there are tourist buses all over everywhere and it is easy to hopscotch to the best parts to ride. LC - One of my favorite things in New Zealand was the ease with which you can get a bus connection, and if you have a folding bike it can be even easier. GK - What were some of your favorite things about riding in New Zealand? Even something as simple as greeting you with a smile when you come into town is great. Just do one small thing and then one small little thing on top of that. So a sign that says 'cyclists welcome here' or a bike lane into town, anything that shows that we realize bikes will come here and we want them here is good. LC - When you're on a bike you feel like the rest of the world doesn't want you there sometimes because a lot of places you go you're running into a lot of friction. Sometimes we'll have fun with them and ask if they let people come in on wheelchairs, and they say "of course." We ask if they allow strollers in, and they say "of course." They don't see what the disconnect is. Sometimes when we start to wheel them in, the hotel is like, "ah ah ah" It's like they don’t realize that this is an important part of our trip. If you're a motel, allow people who come on bike to park the bikes in the rooms. RR - One of the most obvious and simple things that costs hardly anything is just advertising "we welcome bikes" or having some sort of simple signage. GK - You’ve traveled by bike across many places in the US, and now New Zealand, so what do you think are the most essential things communities and regions can do to make bicycle tourism more inviting and encouraged? While they were here, I had the opportunity to ask them a few questions about their travels, and pick their brains a little on promoting bike tourism in Santa Monica. The stunning series of videos and blog posts entitled The Kiwi Chronicles was posted to the Bicycle Times website in installments as they made their way around the Country.Īfter returning to LAX recently from New Zealand, Russ and Laura spent a couple of days hanging out in Santa Monica. Their New Zealand trip was video documented for Bicycle Times, who helped sponsor the adventure. They’ve traveled by bike all across the United States, and more recently they took a tour around New Zealand with Brompton folding bicycles. ![]() In 2009 Laura and Russ decided to cut the cord on having day jobs, sold off the majority of their belongings, and loaded up their bikes to start an open ended journey with some savings and using their talents to make a little money along the way. ![]() 11/9/2023 0 Comments Out of pocket expenses insurance![]() ![]() HSA and HDHP limit increases "are released much earlier than other employee benefit limits so that insurance companies that offer high deductible health plans-which participants must enrolled in to make HSA contributions-can get their insurance products approved by state insurance regulators," explained William Sweetnam, legislative and technical director at the Employers Council on Flexible Compensation (ECFC), which represents sponsors of account-based benefits plans.įamily coverage numbers happened to be twice the individual coverage numbers in recent years but it isn’t always true," Sit pointed out. The catch-up contribution amount, however, is fixed by statute. The contribution limits are adjusted for inflation (rounded to the nearest $50) annually, using the Consumer Price Index for All Urban Consumers for the 12-month period ending on March 31. HDHP maximum out-of-pocket amounts (deductibles, co-payments and other amounts, but not premiums)Ĭontribution limits for various tax-advantaged accounts for the following year are usually announced in October, "except for HSAs, which come out in the latter part of April or May," explained Harry Sit, CEBS, who writes The Finance Buff blog. HSA catch-up contributions (age 55 or older) HSA contribution limit (employer + employee) This means health plans do not need to substantially change their plan designs for 2022.įor Health Savings Accounts and High-Deductible Health Plans "For HSA-qualified insurance plans, the minimum deductibles will remain the same as for 2021, but the annual out-of-pocket maximums will increase slightly for 2022," said Roy Ramthun, president and founder of HSA Consulting Services. Revenue Procedure 2021-25, the IRS confirmed HSA contribution limits effective for calendar year 2022, along with minimum deductible and maximum out-of-pocket expenses for the HDHPs with which HSAs are paired. That's about a 1.4 percent increase from 2021. The annual inflation-adjusted limit on HSA contributions will be $3,650 for self-only and $7,300 for family coverage. Health savings account (HSA) contribution limits for 2022 are going up $50 for self-only coverage and $100 for family coverage, the IRS announced May 10, giving employers that sponsor high-deductible health plans (HDHPs) plenty of time to prepare for open enrollment season later this year. IRS Announces Spike in 2023 Limits for HSAs and High-Deductible Health Plans. Update: On April 29, 2022, the IRS announced health savings account (HSA) contribution limits for 2023. ![]() 11/9/2023 0 Comments Ebay consignment sellers near me![]() ![]() Over the years iSOLD It Central Indiana has added a host of other services- make sure to check them out! We’ll sell it on eBay. We are a trusted selling service for those in Indiana and even neighboring states of Kentucky, Illinois and Ohio.Īnd we are more than an online selling business. Individuals, businesses, & fundraisers get top dollar when we sell online. Customers come from the Central Indiana area and beyond. iSOLD It is the USs largest chain of drop-off stores & the 1 seller on eBay. The concept is simple and sounds great, you find an eBay consignment seller near you, you drop off your stuff there, and you kindly tell them Please sell my. ISOLD It Central Indiana has developed a wide following over our 14 PLUS year history. We also use Amazon, Craigslist,, uBid, and other online sites when advantageous. ![]() Option 2: Fixed Price + Best Offer listing for. Please call us or stop by our store.Īs a Registered eBay Drop-Off Location (REDOL) and Gold level PowerSeller, iSOLD It Central Indiana meets eBay’s most stringent Trading Assistant requirements. eBay Consignment Services Option 1: 7 Day Auction with 5.00 starting bid for cards valued at 5 or more. Save time and rely on our expertise to make e-commerce work best for you. iSOLD It helps individuals, businesses, and fundraisers get top dollar by selling their items online. It only takes me about 10-15 minutes to list and ship each item, so I dont have a. ![]() We are a proud member of the nation’s largest chain of drop-off stores and the #1 seller on eBay. Some eBay sellers only accept items they can sell for 50 or more. As of July 1, iSOLD It Central Indiana has moved, please visit us in our new location! Fog City Auctions 4 Auction Houses Outer Richmond This is a placeholder effort and time by saying I found my guy to declutter and organize my consignment efforts at my. ![]() ![]() This suite includes Word, Excel, PowerPoint, and Outlook. We reviewed Office 2011 Home and Business, which costs $199 for a single install or $279 for three installs if you want to put it on three computers at home or work. This latest Office client for Mac is definitely a solid offering, but how long can Microsoft hold on to its dominance? New Coauthoring requires that you use SharePoint Foundation 2010 for enterprise use, but for personal or small businesses, you can save and access files over SkyDrive (25GB of available online storage) on Windows Live with a free registration.Īll of the new tweaks to the interface and each of the apps in the suite make Office 2011 for Mac a great option, but with the rise of cloud-based computing and online office suites like Google Docs, we wonder how long the big desktop apps like Office will remain on top. One of the major new changes to the suite (on the Windows side, too) is the ability to collaborate and share your work using Web apps. Add the ease of compatibility with a strong feature set across the entire suite and you have a desktop office package that's almost a must-have in both large and small businesses, and even home productivity settings. But if you work with primarily Windows users who use Office, it's tough to beat the automatic compatibility of using the same programs. Certainly many Mac users will look first at Apple's iWork for a productivity suite, and it is a great office suite in its own right. Once we dug deep into the feature set of Office 2011 for Mac, we saw there were several enhancements that made the whole suite better, and some of the niftier tweaks are even Mac-exclusive. Not only has it nearly reached feature parity (and cross compatibility) with the Mac counterparts to Word, Excel, and PowerPoint, but it has finally added Outlook, the e-mail and scheduling client Mac business fans have been clamoring for for years. Though the latest package is still not on par with the Windows version (you get only the four main programs-a big difference when you consider the Windows version has 10), Microsoft made a big leap with this latest version for the Mac in several other ways. Microsoft Office for Mac 2011 offers a solid update to the Word, Excel, PowerPoint, and the other members of the productivity suite. ![]() |
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